Section
1 - Chemical Product and Company Identification
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HMIS |
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H F R |
1 0 0 |
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Product/Chemical Name: Excel-Crete Additive
Manufacturer: Excellent Coatings Inc., 1285 Distribution Way, Vista, CA 92083, Phone (619) 598‑1234, FAX (619)598‑1131.
Section 2 -
Composition / Information on Ingredients
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COMPOSITION/INFORMATION ON INGREDIENTS |
CAS REG NO. |
WT (%) |
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1. Acrylic polymer |
Not Hazardous |
25 |
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2. Individual residual monomers 3. Aqua ammonia 4. Water |
Not Required 1336-21-6 7732-188-5 |
< 0.1 0.2 MAX 75 |
See SECTION 8, Exposure Controls / Personal Protection
Section 3 – Hazards
Identification
Inhalation
Eye Contact
Skin Contact
Inhalation of vapor or mist can cause the following:
- headache – nausea – irritation of nose, throat, and lungs
Direct contact with material can cause the following:
- slight irritation
Section 4 – First Aid
Measures
InhalationMove subject to fresh air. Eye Contact
Flush eyes with a large amount of water for at least 15 minutes. Consult a physician if irritation persists. Skin ContactWash affected skin areas thoroughly with soap and water. Consult a physician if irritation persists. IngestionIf swallowed, give 2 glasses of water to drink. Consult a physician. Never give anything by mouth to an unconscious person |
Section 5 – Fire
Fighting Measures
Auto-ignition Temperature............................................. Not Applicable
Lower Explosive Limit...................................................... Not Applicable
Upper Explosive Limit...................................................... Not Applicable
Material can splatter above 100c/212F. Dried product can burn.
Use extinguishing media appropriate for surrounding fire.
Wear self-contained breathing apparatus (pressure-demand MSHA/NIOSH approved
Or equivalent) and full protective gear.
.
Section 6 – Accidental
Release Measures
Appropriate protective equipment must be worn when handling a spill of this material. See SECTION 8, Exposure Controls/Personal Protection, for recommendations. If exposed to material during clean-up operations, see SECTION 4, First Aid Measures, for actions to follow.
Keep spectators away. Floor may be slippery; use care to avoid falling. Contain spills immediately with inert materials (e.g. sand earth). Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
Section 7 – Handling and Storage
Keep from freezing; material may coagulate. The minimum recommended storage temperature for this material is 1C/34F. The maximum recommended storage temperature for this material is 49C/120F.
Handling Procedures
Monomer vapors can be evolved when material is heated during processing operations. See SECTION d8, Exposure Controls/Personal Protection, for types of ventilation required.
Section 8 - Exposure
Controls / Personal Protection
Exposure Limit
Information
|
No. |
CAS REG NO. |
WT (%) |
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1. Acrylic polymer |
Not Hazardous |
46 |
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2. Individual residual monomers 3. Aqua ammonia 4. Water |
Not Required 1336-21-6 7732-18-5 |
< 0.1 0.2 MAX 54 |
Respiratory Protection
None required if airborne concentrations are maintained below the exposure limit listed in ‘Exposure Limit Information’. For air borne concentrations up to 10 times the TWA/TLV’s listed in “Exposure Limit Information”, wear MSHA/NIOSH approved (or equivalent) half-mask, air-purifying respirator. Air-purifying respirators should be equipped with MSHA/NIOSH approved (or equivalent) cartridges for protection against organic vapors.
Eye Protection
Use chemical splash goggles (ANSI Z87.1 or approved equivalent).
Hand Protection
The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection: -Neoprene
Cont.
Section 8 - Exposure Controls and Personal Protection
Engineering Controls (Ventilation)
Use local exhaust ventilation with a minimum capture velocity of 100 ft/min. (0.5m./sec.) at the point of vapor evolution. Refer to the current edition of industrial Ventilation; A Manual of Recommended Practice published by the American Conference of Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of exhaust systems.
Other
Protective Equipment
Facilities storing or utilizing this material should be equipped with an eyewash facility.
Section 9 – Physical
and Chemical Properties
Appearance....................................... Milky
Color................................................... White
State.................................................... Liquid
Odor Characteristic........................... Ammonia odor
pH........................................................ 9.5 to 10.0
Viscosity............................................ 50 CPS Maximum
Specific Gravity (Water-1)............... 1.0 to 1.2
Vapor Density (Air=1)...................... < 1 Water
Vapor Pressure.................................. 17 mm Hg @ 20C/68F Water
Melting Point..................................... 100 C / 212F Water
Solubility in Water............................ Dilutable
Percent Volatility............................... 52 to 54% Water
Evaporation Rate (Bac = 1).............. < 1 Water
See SECTION 5 Fire Fighting Measures
Section 10 – Stability
and Reactivity
Instability
This material is considered stable. However, avoid temperatures above 177C/350F, the onset of polymer decomposition. Thermal decomposition is dependent on time and temperature.
Hazardous Decomposition Products
Thermal decomposition may yield acrylic monomers.
Hazardous Polymerization
Product will not undergo polymerization.
Incompatibility
There are no known materials which are incompatible with this product.
Section 11 –
Toxicological Information
Acute Date
The information shown in SECTION 3, Hazards Identification, is based on the toxicity profiles for a number of acrylic emulsions that are compositionally similar to this product. Typical date are:
Oral LD50 –rat: > 500 mg/kg
Dermal LD50 –
rabbit; > 500 mg/kg,
Skin irritation –
rabbit: practically non-irritating
Eye irritation –
rabbit: inconsequential irritation
Section 12 –
Ecological Information
No Applicable Data
Section 13 – Disposal
Considerations
Procedure
Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer. Incinerate liquid and contaminated solids in accordance with local, state , and federal regulations.
Section 14 – Transport
Information
US DOT Hazard Class...................... NONREGULATED
Section 15 –
Regulatory Information
Workplace Classification
This product is considered non-hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200)
This product is not a ‘controlled product’ under the Canadian Workplace Hazardous Materials Information System (WHMIS).
SARA Title
3: Section 311/312 Categorizations
(40CFR 370)
This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered by Title III of SARA.
SARA Title
3: Section 313 Information (40CFR 372)
This product does not contain a chemical which is listed in Section 313 at or above de minimis concentrations.
CERCLA
Information (40CFR 302.4)
This material contains no hazardous or extremely hazardous substances as defined by CERCLA or SARA Title III, and releases are therefore not reportable.
United States
All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Pennsylvania
Any material listed as “Not Hazardous” in the CAS REG NO. column of SECTION 2, Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the Pennsylvania Worker and Community Right-to-Know Act.